Monteiro M. R., Ambrozin A. R. P., Lio L. M., Boffo E. F., Tavares L. A., Ferreira M. M. C., Ferreira A. G., "Study of Brazilian Gasoline Quality Using Hydrogen Nuclear Magnetic Resonance (¹H NMR) Spectroscopy and Chemometrics", Energ. Fuel., 23(1), 272–279 (2009).
 

Abstract.
The identification of gasoline adulteration by organic solvents is not an easy task, because compounds that constitute the solvents are already in gasoline composition. In this work, the use of hydrogen nuclear magnetic resonance (¹H NMR) with a statistical approach for identifying gasoline adulteration by organic solvents is described. Both principal component analysis (PCA) and hierarchical cluster analysis (HCA) from NMR data of 47 commercial samples allowed the distinction between conform and nonconform samples. The ¹H NMR-PCA and ¹H NMR-HCA models were evaluated through the analyses of 21 intentionally adulterated samples, which showed a tendency to meet in the nonconform group with the increase of the solvent concentration.

Keywords.
 

Keywords Plus.
Principal Component Analysis; 2-Dimensional Gas Chromatography; Multivariate Calibration; Infrared Spectroscopy; Detection of Adulterations; Statistical Analysis; Commercial Gasoline; FTIR Spectroscopy; Mass Spectroscopy; Identification.